Imagine pulling up to a refueling station and filling your vehicle’s tank with liquid hydrogen, as safe and convenient to handle as gasoline or diesel, without the need for high-pressure tanks or cryogenic storage. This vision of a sustainable future could become a reality if a Calgary, Canada–based company, Ayrton Energy, can scale up its innovative method of hydrogen storage and distribution. Ayrton’s technology could make hydrogen a viable, one-to-one replacement for fossil fuels in existing infrastructure like pipelines, fuel tankers, rail cars, and trucks.

The company’s approach is to use liquid organic hydrogen carriers (LOHCs) to make it easier to transport and store hydrogen. The method chemically bonds hydrogen to carrier molecules, which absorb hydrogen molecules and make them more stable—kind of like hydrogenating cooking oil to produce margarine.

A researcher pours a sample of Ayrton’s LOHC fluid into a vial.Ayrton Energy

The approach would allow liquid hydrogen to be transported and stored in ambient conditions, rather than in the high-pressure, cryogenic tanks (to hold it at temperatures below -252 ºC) currently required for keeping hydrogen in liquid form. It would also be a big improvement on gaseous hydrogen, which is highly volatile and difficult to keep contained.

Founded in 2021, Ayrton is one of several companies across the globe developing LOHCs, including Japan’s Chiyoda and Mitsubishi, Germany’s Covalion, and China’s Hynertech. But toxicity, energy density, and input energy issues have limited LOHCs as contenders for making liquid hydrogen feasible. Ayrton says its formulation eliminates these trade-offs.

Safe, Efficient Hydrogen Fuel for Vehicles

Conventional LOHC technologies used by most of the aforementioned companies rely on substances such as toluene, which forms methylcyclohexane when hydrogenated. These carriers pose safety risks due to their flammability and volatility. Hydrogenious LOHC Technologies in Erlanger, Germany and other hydrogen fuel companies have shifted toward dibenzyltoluene, a more stable carrier that holds more hydrogen per unit volume than methylcyclohexane, though it requires higher temperatures (and thus more energy) to bind and release the hydrogen. Dibenzyltoluene hydrogenation occurs at between 3 and 10 megapascals (30 and 100 bar) and 200–300 ºC, compared with 10 MPa (100 bar), and just under 200 ºC for methylcyclohexane.

Ayrton’s proprietary oil-based hydrogen carrier not only captures and releases hydrogen with less input energy than is required for other LOHCs, but also stores more hydrogen than methylcyclohexane can—55 kilograms per cubic meter compared with methylcyclohexane’s 50 kg/m³. Dibenzyltoluene holds more hydrogen per unit volume (up to 65 kg/m³), but Ayrton’s approach to infusing the carrier with hydrogen atoms promises to cost less. Hydrogenation or dehydrogenation with Ayrton’s carrier fluid occurs at 0.1 megapascal (1 bar) and about 100 ºC, says founder and CEO Natasha Kostenuk. And as with the other LOHCs, after hydrogenation it can be transported and stored at ambient temperatures and pressures.

Judges described [Ayrton's approach] as a critical technology for the deployment of hydrogen at large scale.” —Katie Richardson, National Renewable Energy Lab

Ayrton’s LOHC fluid is as safe to handle as margarine, but it’s still a chemical, says Kostenuk. “I wouldn’t drink it. If you did, you wouldn’t feel very good. But it’s not lethal,” she says.

Kostenuk and fellow Ayrton cofounder Brandy Kinkead (who serves as the company’s chief technical officer) were originally trying to bring hydrogen generators to market to fill gaps in the electrical grid. “We were looking for fuel cells and hydrogen storage. Fuel cells were easy to find, but we couldn’t find a hydrogen storage method or medium that would be safe and easy to transport to fuel our vision of what we were trying to do with hydrogen generators,” Kostenuk says. During the search, they came across LOHC technology but weren’t satisfied with the trade-offs demanded by existing liquid hydrogen carriers. “We had the idea that we could do it better,” she says. The duo pivoted, adjusting their focus from hydrogen generators to hydrogen storage solutions.

“Everybody gets excited about hydrogen production and hydrogen end use, but they forget that you have to store and manage the hydrogen,” Kostenuk says. Incompatibility with current storage and distribution has been a barrier to adoption, she says. “We’re really excited about being able to reuse existing infrastructure that’s in place all over the world.” Ayrton’s hydrogenated liquid has fuel-cell-grade (99.999 percent) hydrogen purity, so there’s no advantage in using pure liquid hydrogen with its need for subzero temperatures, according to the company.

The main challenge the company faces is the set of issues that come along with any technology scaling up from pilot-stage production to commercial manufacturing, says Kostenuk. “A crucial part of that is aligning ourselves with the right manufacturing partners along the way,” she notes.

Asked about how Ayrton is dealing with some other challenges common to LOHCs, Kostenuk says Ayrton has managed to sidestep them. “We stayed away from materials that are expensive and hard to procure, which will help us avoid any supply chain issues,” she says. By performing the reactions at such low temperatures, Ayrton can get its carrier fluid to withstand 1,000 hydrogenation-dehydrogenation cycles before it no longer holds enough hydrogen to be useful. Conventional LOHCs are limited to a couple of hundred cycles before the high temperatures required for bonding and releasing the hydrogen breaks down the fluid and diminishes its storage capacity, Kostenuk says.

Breakthrough in Hydrogen Storage Technology

In acknowledgement of what Ayrton’s nontoxic, oil-based carrier fluid could mean for the energy and transportation sectors, the U.S. National Renewable Energy Lab (NREL) at its annual Industry Growth Forum in May named Ayrton an “outstanding early-stage venture.” A selection committee of more than 180 climate tech and cleantech investors and industry experts chose Ayrton from a pool of more than 200 initial applicants, says Katie Richardson, group manager of NREL’s Innovation and Entrepreneurship Center, which organized the forum. The committee based its decision on the company’s innovation, market positioning, business model, team, next steps for funding, technology, capital use, and quality of pitch presentation. “Judges described Ayrton’s approach as a critical technology for the deployment of hydrogen at large scale,” Richardson says.

As a next step toward enabling hydrogen to push gasoline and diesel aside, “we’re talking with hydrogen producers who are right now offering their customers cryogenic and compressed hydrogen,” says Kostenuk. “If they offered LOHC, it would enable them to deliver across longer distances, in larger volumes, in a multimodal way.” The company is also talking to some industrial site owners who could use the hydrogenated LOHC for buffer storage to hold onto some of the energy they’re getting from clean, intermittent sources like solar and wind. Another natural fit, she says, is energy service providers that are looking for a reliable method of seasonal storage beyond what batteries can offer. The goal is to eventually scale up enough to become the go-to alternative (or perhaps the standard) fuel for cars, trucks, trains, and ships.

Zettabytes—that’s 10²¹ bytes—of data are currently generated every year. All of those cat videos have to be stored somewhere, and DNA is a great storage medium; it has amazing data density and is stable over millennia.

To date, people have encoded information into DNA the same way nature has, by linking the four nucleotide bases comprising DNA—A, T,  C, and G—into a particular genetic sequence. Making these sequences is time-consuming and expensive, though, and the longer your sequence, the higher chance there is that errors will creep in.

But DNA has an added layer of information encoded on top of the nucleotide sequence, known as epigenetics. These are chemical modifications to the nucleotides, specifically altering a C when it comes before a G. In cells, these modifications function kind of like stage directions; they can tell the cell when to use a particular DNA sequence without altering the “text” of the sequence itself. A new paper in Nature describes using epigenetics to store information in DNA without needing to synthesize new DNA sequences every time.

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Clark Johnson says he has wanted to be a scientist ever since he was 3. At age 8, he got bored with a telegraph-building kit he received as a gift and repurposed it into a telephone. By age 12, he set his sights on studying physics because he wanted to understand how things worked at the most basic level.

“I thought, mistakenly at the time, that physicists were attuned to the left ear of God,” Johnson says.

Clark Johnson

Employer

Wave Domain

Title

CFO

Member grade

Life Fellow

After graduating at age 19 with a bachelor’s degree in physics in 1950 from the University of Minnesota Twin Cities, he was planning to go to graduate school when he got a call from the head of the physics section at 3M’s R&D laboratory with a job offer. Tempted by the promise of doing things with his own hands, Johnson accepted the role of physicist at the company’s facility in St. Paul, Minn. Thus began his more than seven-decade-long career as an electrical engineer, inventor, and entrepreneur—which continues to this day.

Johnson, an IEEE Life Fellow, is an active member of the IEEE Magnetics Society and served as its 1983–1984 president.

He was on the science committee of the U.S. House of Representatives, and then was recruited by the Advanced Research Projects Agency (ARPA) and assigned to assist in MIT’s Research Program on Communications Policy, where he contributed to the development of HDTV.

He went on to help found Wave Domain in Monson, Mass. Johnson and his Wave Domain collaborators have been granted six patents for their latest invention, a standing-wave storage (SWS) system that houses archival data in a low-energy-use, tamper-proof way using antiquated photography technology.

3M, HDTV, and a career full of color

3M turned out to be fertile ground for Johnson’s creativity.

“You could spend 15 percent of your time working on things you liked,” he says. “The president of the company believed that new ideas sort of sprung out of nothing, and if you poked around, you might come across something that could be useful.”

Johnson’s poking around led him to contribute to developing an audio tape cartridge and Scotchlite, the reflective film seen on roads, signs, and more.

In 1989 he was tapped to be an IEEE Congressional Fellow. He chose to work with Rep. George Brown Jr., a Democrat representing the 42nd district in central California. Brown was a ranking member of the House committee on science, space, and technology, which oversees almost all non-defense and non-health related research.

“It was probably the most exciting year of my entire life,” Johnson says.

While on the science committee, he met Richard Jay Solomon, who was associate director of MIT’s Research Program on Communications Policy, testifying for the committee on video and telecom issues. Solomon’s background is diverse. He studied physics and electrical engineering in the early 1960s at Brooklyn Polytechnic and general science at New York University. Before becoming a research associate at MIT in 1969, he held a variety of positions. He ran a magazine about scientific photography, and he founded a business that provided consulting on urban planning and transportation. He authored four textbooks on transportation planning, three of which were published by the American Society of Civil Engineers. At the magazine, Solomon gained insights into arcane, long-forgotten 19th-century photographic processes that turned out to be useful in future inventions.

Johnson and Solomon bonded over their shared interest in trains. Johnson’s refurbished Pullman car has traveled some 850,000 miles across the continental U.S.Clark Johnson

Johnson and Solomon clicked over a shared interest in trains. At the time they met, Johnson owned a railway car that was parked in the District of Columbia’s Union Station, and he used it to move throughout North America, traveling some 850,000 miles before selling the car in 2019. Johnson and Solomon shared many trips aboard the refurbished Pullman car.

Now they are collaborators on a new method to store big data in a tamperproof, zero-energy-cost medium.

Conventional storage devices such as solid-state drives and hard disks take energy to maintain, and they might degrade over time, but Johnson says the technique he, Solomon, and collaborators developed requires virtually no energy and can remain intact for centuries under most conditions.

Long before collaborating on their latest project, Johnson and Solomon teamed up on another high-profile endeavor: the development of HDTV. The project arose through their work on the congressional science committee.

In the late 1980s, engineers in Japan were working on developing an analog high-definition television system.

“My boss on the science committee said, ‘We really can’t let the Japanese do this. There’s all this digital technology and digital computers. We’ve got to do this digitally,’” Johnson says.

That spawned a collaborative project funded by NASA and ARPA (the predecessor of modern-day DARPA). After Johnson’s tenure on the science committee ended, he and Solomon joined a team at MIT that participated in the collaboration. As they developed what would become the dominant TV technology, Johnson and Solomon became experts in optics. Working with Polaroid, IBM, and Philips in 1992, the team demonstrated the world’s first digital, progressive-scanned, high-definition camera at the annual National Association of Broadcasters conference.

A serendipitous discovery

Around 2000, Clark and Solomon, along with a new colleague, Eric Rosenthal, began working as independent consultants to NASA and the U.S. Department of Defense. Rosenthal had been a vice president of research and development at Walt Disney Imagineering and general manager of audiovisual systems engineering at ABC television prior to joining forces with Clark and Solomon.

While working on one DARPA-funded project, Solomon stumbled upon a page in a century-old optics textbook that caught his eye. It described a method developed by noted physicist Gabriel Lippmann for producing color photographs. Instead of using film or dyes, Lippmann created photos by using a glass plate coated with a specially formulated silver halide emulsion.

When exposed to a bright, sunlit scene, the full spectrum of light reflected off a mercury-based mirror coating on the back of the glass. It created standing waves inside the emulsion layer of the colors detected. The silver grains in the brightest parts of the standing wave became oxidized, as if remembering the precise colors they saw. (It was in stark contrast to traditional color photographs and television, which store only red, green, and blue parts of the spectrum.) Then, chemical processing turned the oxidized silver halide grains black, leaving the light waves imprinted in the medium in a way that is nearly impossible to tamper with. Lippmann received the 1908 Nobel Prize in Physics for his work.

Lippmann’s photography technique did not garner commercial success, because there was no practical way to duplicate the images or print them. And at the time, the emulsions needed the light to be extremely bright to be properly imprinted in the medium.

Nevertheless, Solomon was impressed with the durability of the resulting image. He explained the process to his colleagues, who recognized the possibility of using the technique to store information for archival purposes. Johnson saw Lippmann’s old photographs at the Museum for Photography, in Lausanne, Switzerland, where he noticed that the colors appeared clear and intense despite being more than a century old.

The silver halide method stuck with Solomon, and in 2013 he and Johnson returned to Lippmann’s emulsion photography technique.

“We got to talking about how we could take all this information we knew about color and use it for something,” Johnson says.

Data in space and on land

While Rosenthal was visiting the International Space Station headquarters in Huntsville, Ala., in 2013, a top scientist said, “‘The data stored on the station gets erased every 24 hours by cosmic rays,’” Rosenthal recalls. “‘And we have to keep rewriting the data over and over and over again.’” Cosmic rays and solar flares can damage electronic components, causing errors or outright erasures on hard disks and other traditional data storage systems.

Rosenthal, Johnson, and Solomon knew that properly processed silver halide photographs would be immune to such hazards, including electromagnetic pulses from nuclear explosions. The team examined Lippmann’s photographic emulsion anew.

Solomon’s son, Brian Solomon, a professional photographer and a specialist in making photographic emulsions, also was concerned about the durability of conventional dye-based color photographs, which tend to start fading after a few decades.

The team came up with an intriguing idea: Given how durable Lippmann’s photographs appeared to be, what if they could use a similar technique—not for making analog images but for storing digital data? Thus began their newest engineering endeavor: changing how archival data—data that doesn’t need to be overwritten but simply preserved and read occasionally—is stored.

The standing wave storage technique works by shining bright LEDs onto a specially formulated emulsion of silver grains in gelatin. The light reflects off the substrate layer (which could be air), and forms standing waves in the emulsion. Standing waves oxidize the silver grains at their peaks, and a chemical process turns the oxidized silver grains black, imprinting the pattern of colors into the medium. Wave Domain

Conventionally stored data sometimes is protected by making multiple copies or continuously rewriting it, Johnson says. The techniques require energy, though, and can be labor-intensive.

The amount of data that needs to be stored on land is also growing by leaps and bounds. The market for data centers and other artificial intelligence infrastructure is growing at an annual rate of 44 percent, according to Data Bridge Market Research. Commonly used hard drives and solid-state drives consume some power, even when they are not in use. The drives’ standby power consumption varies between 0.05 and 2.5 watts per drive. And data centers contain an enormous number of drives requiring tremendous amounts of electricity to keep running.

Johnson estimates that about 25 percent of the data held in today’s data centers is archival in nature, meaning it will not need to be overwritten.

The ‘write once, read forever’ technology

The technology Johnson, Solomon, and their collaborators have developed promises to overcome the energy requirements and vulnerabilities of traditional data storage for archival applications.

The design builds off of Lippmann’s idea. Instead of taking an analog photograph, the team divided the medium into pixels. With the help of emulsion specialist Yves Gentet, they worked to improve Lippmann’s emulsion chemistry, making it more sensitive and capable of storing multiple wavelengths at each pixel location. The final emulsion is a combination of silver halide and extremely hardened gelatin. Their technique now can store up to four distinct narrow-band, superimposed colors in each pixel.

The standing wave storage technique can store up to four colors out of a possible 32 at each pixel location. This adds up to an astounding storage capacity of 4.6 terabits (or roughly 300 movies) in the area of a single photograph. Wave Domain

“The textbooks say that’s impossible,” Solomon says, “but we did it, so the textbooks are wrong.”

For each pixel, they can choose four colors out of a possible 32 to store.

That amounts to more than 40,000 possibilities. Thus, the technique can store more than 40,000 bits (although the format need not be binary) in each 10-square-micrometer pixel, or 4.6 terabits in a 10.16 centimeter by 12.7 cm modified Lippmann plate. That’s more than 300 movies’ worth of data stored in a single picture.

To write on the SWS medium, the plate—coated with a thin layer of the specially formulated emulsion—is exposed to light from an array of powerful color LEDs.

That way, the entire plate is written simultaneously, greatly reducing the writing time per pixel.

The plate then gets developed through a chemical process that blackens the exposed silver grains, memorizing the waves of color it was exposed to.

Finally, a small charged-couplet-device camera array, like those used in cellphones, reads out the information. The readout occurs for the entire plate at once, so the readout rate, like the writing rate, is fast.

“The data that we read is coming off the plate at such a high bandwidth,” Solomon says. “There is no computer on the planet that can absorb it without some buffering.”

The entire memory cell is a sandwich of the LED array, the photosensitive plate, and the CCD. All the elements use off-the-shelf parts.

“We took a long time to figure out how to make this in a very inexpensive, reproducible, quick way,” Johnson says. “The idea is to use readily available parts.” The entire storage medium, along with its read/write infrastructure, is relatively inexpensive and portable.

To test the durability of their storage method, the team sent their collaborators at NASA some 150 samples of their SWS devices to be hung by astronauts outside the International Space Station for nine months in 2019. They then tested the integrity of the stored data after the SWS plates were returned from space, compared with another 150 plates stored in Rosenthal’s lab on the ground.

“There was absolutely zero degradation from nine months of exposure to cosmic rays,” Solomon says. Meanwhile, the plates on Rosenthal’s desk were crawling with bacteria, while the ISS plates were sterile. Silver is a known bactericide, though, so the colors were immune, Solomon says.

Their most recent patent, granted earlier this year, describes a method of storing data that requires no power to maintain when not actively reading or writing data. Team members say the technique is incorruptible: It is immune to moisture, solar flares, cosmic rays, and other kinds of radiation. So, they argue, it can be used both in space and on land as a durable, low-cost archival data solution.

Passing on the torch

The new invention has massive potential applications. In addition to data centers and space applications, Johnson says, scientific enterprises such as the Rubin Observatory being built in Chile, will produce massive amounts of archival data that could benefit from SWS technology.

“It’s all reference data, and it’s an extraordinary amount of data that’s being generated every week that needs to be kept forever,” Johnson says.

Johnson says, however, that he and his team will not be the ones to bring the technology to market: “I’m 94 years old, and my two partners are in their 70s and 80s. We’re not about to start a company.”

He is ready to pass on the torch. The team is seeking a new chief executive to head up Wave Domain, which they hope will continue the development of SWS and bring it to mass adoption.

Johnson says he has learned that people rarely know which new technologies will eventually have the most impact. Perhaps, though few people are aware of it now, storing big data using old photographic technology will become an unexpected success.